PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

Ta có: \(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)

Theo PT: \(n_{O_2\left(LT\right)}=\dfrac{1}{2}n_{KMnO_4}=0,1\left(mol\right)\)

Mà: H% = 80%

\(\Rightarrow n_{O_2\left(TT\right)}=0,1.80\%=0,08\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,08.22,4=1,792\left(l\right)\)

PT: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

Ta có: \(n_P=\dfrac{3,1}{31}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{4}>\dfrac{0,08}{5}\), ta được P dư.

Theo PT: \(n_{P\left(pư\right)}=\dfrac{4}{5}n_{O_2}=0,064\left(mol\right)\)

\(\Rightarrow n_{P\left(dư\right)}=0,1-0,064=0,036\left(mol\right)\)

\(\Rightarrow m_{P\left(dư\right)}=0,036.31=1,116\left(g\right)\)

Bạn tham khảo nhé!

\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

               1<------------------------------------0,5

=> \(m_{KMnO_4\left(pthh\right)}=1.158=158\left(g\right)\)

=> \(m_{KMnO_4\left(tt\right)}=\dfrac{158.100}{80}=197,5\left(g\right)\)

PTHH: \(Cu_2S+2O_2\xrightarrow[]{t^o}2CuO+SO_2\)

a) Ta có: \(n_{Cu_2S}=\dfrac{100}{160}=0,625\left(mol\right)\) \(\Rightarrow n_{O_2\left(lýthuyết\right)}=1,25\left(mol\right)\)

\(\Rightarrow V_{O_2\left(thực\right)}=\dfrac{1,25\cdot22,4}{96\%}\approx29,17\left(l\right)\)

b) Sửa đề: "Tính khối lượng KMnO₄ để hấp thụ hết SO₂"

PTHH: \(5SO_2+2KMnO_4+2H_2O\rightarrow K_2SO_4+2MnSO_4+2H_2SO_4\)

Ta có: \(n_{SO_2\left(thực\right)}=n_{Cu_2S}\cdot96\%=0,6\left(mol\right)\)

\(\Rightarrow n_{KMnO_4}=0,24\left(mol\right)\) \(\Rightarrow m_{KMnO_4}=0,24\cdot158=37,92\left(g\right)\)

c) PTHH: \(SO_2+\dfrac{1}{2}O_2\xrightarrow[V_2O_5]{t^o}SO_3\)

Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{SO_2}=0,3\left(mol\right)\) \(\Rightarrow V_{kk}=\dfrac{0,3\cdot22,4}{21\%}=32\left(l\right)\)

d) Bảo toàn nguyên tố Lưu huỳnh: \(n_{H_2SO_4\left(lýthuyết\right)}=n_{SO_2\left(thực\right)}=0,3\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(thực\right)}=0,3\cdot85\%=0,255\left(mol\right)\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,255\cdot98}{10\%}=249,9\left(g\right)\)

a. \(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)

\(n_{KMnO_4}=0,6mol\)

\(\rightarrow n_{O_2}=\frac{1}{2}n_{KMnO_4}=0,3mol\)

\(\rightarrow V_{O_2}=6,72l\)

\(V_{O_2\text{thực}}=\frac{6,72.75}{100}=5,04l\)

b. \(2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2\)

\(n_{O_2}=1,5mol\)

\(\rightarrow n_{KMnO_4}=2n_{O_2}=3mol\)

\(\rightarrow m_{KMnO_4\text{cần}}=\frac{474.100}{80}=592,5g\)

\(n_{KMnO_4} = \dfrac{40.(100\%-21\%)}{158} = 0,2(mol)\\ n_{KMnO_4\ pư} = 0,2.80\% = 0,16(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{O_2} = \dfrac{1}{2}n_{KMnO_4\ pư} = 0,08(mol)\\ m_{O_2} = 0,08.32 = 2,56(gam)\)

bn ơi cho mình hỏi 80% K2MnO4 của riêng hc hay là all sản phẩm?

\(\%m_{KMnO_4}=100\%-21\%=79\%\)

\(m_{KMnO_4}=40.79\%=31,6g\)

\(n_{KMnO_4}=\frac{31,6}{158}=0,2mol\)

\(n_{KMnO_4\text{phản ứng}}=80\%.0,2=0,16mol\)

PTHH: \(2KMnO_4\rightarrow^{t^o}K_2MnO_4+MnO_2+O_2\uparrow\)

Từ phương trình \(n_{O_2}=\frac{1}{2}.n_{KMnO_4\text{phản ứng}}=0,08mol\)

\(m_{O_2}=32.0,08=2,56g\)

D
B

D

B

D-B

\(n_{KMnO_4}=\dfrac{63,2}{158}=0,4\left(mol\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
            0,4                                             0,2 
=> \(V_{O_2\left(lt\right)}=0,2.22,4=4,48\left(l\right)\\ V_{O_2\left(tt\right)}=\dfrac{90.4,48}{100}=4,032\left(l\right)\) 
 

a) \(2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\)

b)

\(n_{KClO_3} = \dfrac{36,75}{122,5} = 0,3(mol)\)

Theo PTHH : 

\(n_{KCl} = n_{KClO_3} = 0,3(mol)\\ \Rightarrow m_{KCl} = 0,3.74,5 = 22,35(gam)\\ \Rightarrow m_{O_2} = m_{KClO_3} - m_{KCl} = 14,4(gam)\)

c)

Bảo toàn khối lượng : 

\(m_{O_2} = 25 - 15,4 = 9,6(gam)\\ \Rightarrow n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{KClO_3} = 0,2.122,5 = 24,5(gam)\\ \%m_{tạp\ chất}= \dfrac{25-24,5}{25}.100\% = 2\%\)

\(a.\)

\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)

\(b.\)

\(n_{KClO_3}=\dfrac{36.75}{122.5}=0.3\left(mol\right)\)

\(\Rightarrow n_{O_2}=\dfrac{3}{2}n_{KClO_3}=\dfrac{3}{2}\cdot0.3=0.45\left(mol\right)\)

\(m_{O_2}=0.45\cdot32=14.4\left(g\right)\)

\(m_{KCl}=0.3\cdot74.5=22.35\left(g\right)\)

\(c.\)

\(2KClO_3\underrightarrow{t^0}2KCl+3O_2\)

\(a.............a\)

\(m_{Cr}=m_{KCl}+m_{tc}=25-122.5a+74.5a=15.4\left(g\right)\)

\(\Rightarrow a=0.2\)

\(m_{O_2}=\dfrac{3}{2}\cdot0.2\cdot32=9.6\left(g\right)\)

\(m_{KClO_3}=0.2\cdot122.5=24.5\left(g\right)\)

\(m_{tc}=25-24.5=0.5\left(g\right)\)

\(\%m_{Tc}=\dfrac{0.5}{25}\cdot100\%-2\%\)